1,4-Butanediol

    • Product Name: 1,4-Butanediol
    • Chemical Name (IUPAC): butane-1,4-diol
    • CAS No.: 110-63-4
    • Chemical Formula: C4H10O2
    • Form/Physical State: Liquid
    • Factroy Site: No.3369 Bohai 10th Road, Lingang Economic Zone, Binhai New Area, Tianjin City, China
    • Price Inquiry: sales2@liwei-chem.com
    • Manufacturer: Tianjin Soda Plant
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    Specifications

    HS Code

    413710

    Chemicalname 1,4-Butanediol
    Casnumber 110-63-4
    Molecularformula C4H10O2
    Molarmass 90.12 g/mol
    Appearance Colorless, oily liquid
    Odor Mild
    Density 1.017 g/cm³ at 20°C
    Meltingpoint 20.1°C
    Boilingpoint 230°C
    Solubilityinwater Miscible
    Refractiveindex 1.446 at 20°C
    Flashpoint 121°C (closed cup)

    As an accredited 1,4-Butanediol factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The 1,4-Butanediol is packaged in a 25-liter blue HDPE drum with a secure screw cap and clear hazard labels.
    Container Loading (20′ FCL) 20′ FCL container loading for 1,4-Butanediol involves bulk or drum packaging, maximizing space and ensuring safe, secure chemical transport.
    Shipping 1,4-Butanediol is shipped in tightly sealed containers, typically drums or intermediate bulk containers (IBCs), to prevent moisture absorption and contamination. It should be transported under ambient conditions, away from heat and incompatible substances. Proper labeling and documentation are required, adhering to regulations for chemical transport and safety standards.
    Storage 1,4-Butanediol should be stored in tightly closed containers, in a cool, dry, and well-ventilated area away from heat and sources of ignition. It should be protected from moisture and incompatible materials such as oxidizing agents. Storage areas should be equipped with spill containment, and containers should be clearly labeled. Avoid prolonged exposure to air to minimize degradation.
    Shelf Life 1,4-Butanediol has a typical shelf life of 2 years when stored properly in sealed containers, cool, and dry conditions.
    Application of 1,4-Butanediol

    Purity 99.9%: 1,4-Butanediol with 99.9% purity is used in high-performance polyester synthesis, where it ensures optimal polymer chain integrity and clarity.

    Low Water Content: 1,4-Butanediol with water content less than 0.03% is used in thermoplastic polyurethane production, where it minimizes bubble formation and material defects.

    Molecular Weight 90.12 g/mol: 1,4-Butanediol with molecular weight of 90.12 g/mol is used in elastic fiber manufacturing, where it provides consistent elongation and tensile strength.

    Melting Point 20.1°C: 1,4-Butanediol with a melting point of 20.1°C is used in biodegradable solvent formulations, where it ensures stable liquid-phase processing at room temperature.

    Viscosity 75 mPa·s: 1,4-Butanediol with a viscosity of 75 mPa·s is used in surface coating applications, where it enhances spreadability and uniform film formation.

    Stability Temperature 120°C: 1,4-Butanediol with thermal stability up to 120°C is used in resin manufacturing, where it supports sustained performance under elevated processing temperatures.

    Color Index APHA <10: 1,4-Butanediol with APHA color index less than 10 is used in optical polymer applications, where it allows for high transparency and minimal discoloration.

    Acid Value <0.1 mg KOH/g: 1,4-Butanediol with acid value below 0.1 mg KOH/g is used in spandex production, where it prevents degradation and ensures elastic consistency.

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    Certification & Compliance
    More Introduction

    1,4-Butanediol: Experience from Our Production Floor

    Introduction to 1,4-Butanediol in Modern Chemistry

    Working in chemical manufacturing, hands-on experience goes beyond academic formulas and theory. 1,4-Butanediol (BDO)—with the chemical formula C4H10O2—proves this every day in our plant. Decades of real-world performance underpin our confidence when introducing this product. BDO starts as a clear, viscous liquid with a mild, slightly sweet scent. On the shop floor, certain things signal genuine quality: consistent purity, reliable reactivity, robust supply. Through such experience, we have built our approach to producing and supplying BDO that meets consistently high benchmarks for industrial partners.

    Understanding the Core: Our 1,4-Butanediol

    We manufacture 1,4-butanediol in a dedicated facility where quality checks and safety standards take center stage. Each batch runs through carefully controlled processes—catalytic hydrogenation remains the most reliable route. For years, methanol and formaldehyde serve as key raw materials, and the process demands constant monitoring: temperatures, pressures, reaction times, all logged for full traceability. Purity isn’t just about a number on a spec sheet; it directly shapes downstream product outcomes. We regularly produce 1,4-butanediol at >99.5% purity, supported by gas chromatography and titration. Removing water, by-products, and trace impurities requires diligence, and achieving colorless clarity signals careful distillation and storage.

    Over time, we have learned that the finer details—such as the nickel catalyst’s lifetime and the condition of the stainless steel reactors—greatly affect output reliability. Every maintenance cycle, every pressure check, tells part of the BDO narrative. We do not simply ship barrels of a common solvent; we deliver decades of experience, methodical testing, and cultivated expertise in making sure what leaves our facility meets expectations of operators around the world.

    BDO: What Sets It Apart from Glycols and Solvents

    1,4-Butanediol often joins plant rosters with other glycols, like ethylene glycol and propylene glycol. Operators and chemists often ask what sets BDO apart. On a molecular level, BDO’s straight four-carbon chain offers unique functionality. Unlike ethylene glycol (with its simpler two-carbon structure), 1,4-butanediol delivers better flexibility for certain polymer reactions. BDO converts easily to high-performance plastics, including polybutylene terephthalate (PBT). Thermal stability and lower volatility can give it an edge in processes requiring extended reaction times or higher operating temperatures.

    The slight sweetness of BDO’s odor might recall other liquid glycols, but the similarities mostly end there. BDO exhibits higher boiling points and viscosity—this influences how it blends in resin production, polyurethane dispersions, or textile spinning baths. Ethylene glycol or propylene glycol may act as primary antifreeze agents, but BDO finds greater demand in areas where mechanical or plastic properties matter. From our perspective in the plant, every drum of BDO sets out with a distinct destination: producers of elastic spandex fibers, engineering-grade plastics, or solvents for the pharmaceutical sector.

    Our Model Range and Typical Specifications

    Consistency stands at the forefront of manufacturing success. Over the years, our flagship model for BDO keeps the following profile: a purity above 99.5%, water content below 0.1%, and traces of aldehydes or other organics below parts per million. In physical handling, BDO’s viscosity can create challenges—chilling temperatures may start to solidify the liquid. We maintain heated storage and insulated transfer lines, especially during winter months. Prepping tanks and verifying pump integrity becomes a way of life; even small leaks or pressure drops can spell financial and environmental risk.

    Many producers of spandex, thermoplastic polymers, and specialty solvents demand extra documentation. For us, it means running further contaminant screens and keeping packaging—drums, ISO tanks, and flexi-bags—spotlessly dry and sealed. From receiving raw material audit reports to issuing certificates of analysis, every step integrates lessons from years of mishaps and improved procedures. The logistics team pays special attention to weight checks, loading temperatures, and sealing protocols so that customers open compliant shipments, not costly surprises.

    Usage in Industry: Experiences from Our Partners

    BDO’s main stage remains in plastics and textile chemistry. Week after week, we send tanker loads to spandex fiber producers who run world-class facilities. In spandex synthesis, BDO provides the diol unit that joins with diisocyanates or polyesters, creating elastic chains found in countless sportswear items. Any inconsistency in BDO purity can ripple through the entire fiber extrusion line, causing production stops or weak spots in the finished material. We’ve seen that first-hand—long before adjusting our specifications and inspections. Avoiding those pitfalls requires more than published parameters; it means knowing how small impurities align with in-plant troubleshooting.

    We also supply to automotive polymer plants, where polybutylene terephthalate (PBT) forms tough, heat-resistant parts for connectors and gear housings. Here, water content in BDO makes the difference between high-molecular-weight plastics and off-grade, brittle material. Even after years of use, some partners call for advice troubleshooting odd reactivity issues caused by shipping delays or sub-optimal storage. By knowing both the chemistry and the reality of production, we can suggest adjustments—a tank flush, inert gas purging, or new heating procedures—that limit downtime and keep product flow steady.

    Pharmaceutical and Specialty Uses

    Not all our BDO serves the plastics and fibers market. We regularly work with pharmaceutical and fine chemical companies that require BDO as a solvent or intermediate for synthesizing active compounds. By designing our purification sequences to meet these needs, we help achieve precise control over residual organic acids and aldehydes. Even trace contaminants can affect downstream pharmaceutical reactions, so we dedicate small-volume production runs with tailored QA checks. Handling customer audits for pharma applications has shown us the value of enhanced documentation and collaborative troubleshooting, well beyond routine deliveries.

    BDO’s solvent power and stability in neutral to basic pH lays groundwork for synthesizing gamma-butyrolactone (GBL), a precursor that finds legitimate industrial use in polymers and specialty chemicals. Regulatory scrutiny requires us to monitor where and how our BDO enters supply chains. We keep up with compliance requirements, working transparently with authorities. By providing both technical and regulatory guidance to customers, we build reputational trust—a resource no specification can replace.

    BDO: Field Comparisons and Lessons Learned

    No chemical operator wants downtime or reject batches—each carries real costs and disrupts supply chains. We receive requests for BDO alternatives from operators used to working with ethylene glycol, diethylene glycol, or tetrahydrofuran (THF). None fills exactly the same shoes. Glycols like EG or DEG offer lower costs and easier handling at cold temperatures, yet they often fall short in polymer performance or solvent strength. Tetrahydrofuran, a cyclic ether derivative of BDO, displays outstanding solvent properties and serves in specialty resins, but its volatility and flammability drive up operational risks and insurance costs.

    Direct use of BDO brings mechanical stability to polyesters and polyurethanes that lesser diols can’t always match. Higher boiling points and solidification at lower temperatures call for more attention to transfer systems: we have learned to avoid undersized tank heaters, maintain flexible hoses, and equip all bulk lines with quick-disconnects and temperature alarms. Maintenance departments see long-term payoff: less product loss during cold snaps, fewer blockages, and safer unloading procedures. By designing systems with BDO’s challenges in mind, operators avoid production slowdowns and frequent call-outs.

    Environmental and Safety Commitments

    Operating chemical production plants means balancing high-volume output with environmental and human safety. 1,4-Butanediol, despite proven industrial value, must be handled with full knowledge of its toxicity risks and potential misuse. Spills can lead to local pollution, especially near sensitive waterways; strict secondary containment and regular facility audits prevent such incidents in our experience. Operators handling BDO undergo specific training—gloves, goggles, and chemical-resistant clothing are standard equipment for transfer and loading.

    We invest in closed-loop vapor recovery systems to minimize atmospheric discharges. In loading docks and pump rooms, portable analyzers check for vapor leaks. All outgoing shipments carry batch documentation with hazard designations and emergency instructions, shaped by years of responding to customer queries and official inspections. Periodic drills with local emergency responders help define best practice for BDO response—this isn’t abstract theory, but lived experience from incidents over the years.

    Quality Control: Beyond the Certificate of Analysis

    It’s easy to think quality stops at paperwork, but running a plant tells a different story. Every shipment—whether drum, IBC, or bulk tank—draws from tanks that may have held BDO for days or weeks. We sample and test, but also rely on tracking residual water condensation, pump wear, and tank bottom buildup. We see most off-spec events from unforeseen temperature fluctuations or small valve leaks, not from upstream supplier issues.

    We keep spare parts for transfer pumps and pressure sensors, and every shift operator undergoes detailed checklists before transferring BDO. If contamination occurs, we perform full system flushes, not just spot cleaning. Experience has taught us that cost-cutting can backfire quickly: a leaky flange or undersized steam trap costs far more in downtime and lost product than proper maintenance cycles. As manufacturers, not just traders, we retain ultimate responsibility for what arrives at customer sites.

    BDO’s Evolving Role in a Changing Market

    Economic cycles and regulatory changes routinely influence BDO demand—and reliable manufacturers field questions every cycle. In recent years, rising demand for biodegradable plastics and green textile fibers has increased requests for higher-purity, specialty BDO. At the same time, tighter controls on precursor chemicals affect which regions can import large BDO shipments. While adjusting to these pressures, we work closely with logistics partners and end users to confirm compliance and minimize disruption.

    Our experience proves that technical support, rapid troubleshooting, and open communication are as vital as the product itself. Some operators experiment with direct BDO hydrogenation for new polyurethanes; others develop test batches of advanced elastomers demanding narrow impurity windows. We encourage plant visits and regular process feedback. Solutions tend to emerge from frank discussions about what worked and what didn’t, not from generic brochures.

    Continuous Improvement and Looking Ahead

    In a plant, learning never finishes. We actively review process data, equipment history, and customer returns—every complaint or compliment prompts review meetings. Our R&D group tests catalysts and separation resins to push purification one step better. We hold training sessions for junior operators, focusing on hands-on problem solving with experienced team leads. Site visits from long-term partners often reveal ways to speed up unloading cycles or improve tank mixing, which feed directly into plant upgrades.

    We knew years ago that simply meeting official regulations would never set us apart. Value comes from delivering BDO backed with technical experience, proactive troubleshooting, and transparent communication. Whether supplying thousands of tons to industrial plastics giants or catering to a niche pharmaceutical project, the same attention goes into each batch. This discipline—formed by daily plant life—drives us to offer a better product, shape industry standards, and cultivate trust among operators relying on consistent, high-quality BDO today and in the challenge-filled years to come.